[1]秦玉芳,曾明敏,赵春宝,等.微波辐射合成PE-AA接枝吸水树脂的研究[J].南京师范大学学报(工程技术版),2012,12(03):080-84.
 Qin Yufang,Zeng Mingmin,Zhao Chunbao.Study on Synthesis of Waste Plastic PE-AA Water-absorbent Resin by Microwave Irradiation[J].Journal of Nanjing Normal University(Engineering and Technology),2012,12(03):080-84.
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微波辐射合成PE-AA接枝吸水树脂的研究
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南京师范大学学报(工程技术版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
12卷
期数:
2012年03期
页码:
080-84
栏目:
出版日期:
2012-09-20

文章信息/Info

Title:
Study on Synthesis of Waste Plastic PE-AA Water-absorbent Resin by Microwave Irradiation
作者:
秦玉芳;曾明敏;赵春宝;
南京信息职业技术学院微电子学院,江苏南京210046
Author(s):
Qin YufangZeng MingminZhao Chunbao
Institute of Microelectronics,Nanjing College of Information Technology,Nanjing 210046,China
关键词:
吸水树脂引发剂吸收交联剂保水性
Keywords:
water absorbent resininitiatoradsorptioncrosslinkerwater retention
分类号:
TQ324.8
摘要:
以废弃聚乙烯(PE)塑料与丙烯酸(AA)及其盐为原料,采用微波加热法接枝共聚合成一种吸水树脂.研究了引发剂用量、交联剂种类、AA中和度对树脂吸水率的影响,发现当引发剂用量为单体的4%、交联剂环氧氯丙烷用量为0.3%,中和度为86%时,吸水率达53.18 g/g.同时研究了树脂的重复吸水率及保水性,发现该树脂的重复吸水效果较好、保水性能良好.通过红外谱图分析,AA与PE成功接枝.
Abstract:
PE-AA Water-absorbent Resin was synthesized with waste plastic PE and acrylic acid( AA) by microwave irradiation. This paper studies on the dosage of initiator,the kind of crosslinker,the effects of AA neutralization degree on water absorption rate. The water absorption rate was 53. 18 g /g,when the dosage of initiator of the mass monomers was 4%,and the crosslinker epoxy chloropropane( based on the mass of monomers) 0. 3%. Studies on the rate of repetition water absorption and water retention of resin found that the resin repetition absorbing effect and the water retention was good. By infrared spectrum analysis,AA and PE have been grafted.

参考文献/References:

[1]邹新禧. 超强吸水剂[M]. 北京: 化学工业出版社,2002. Zou Xinxi. Super Water Absorbent Agent[M]. Beijing: Chemical Industry Press, 2002. ( in Chinese) [2]田巍,白福臣,李天一. 高吸水树脂的发展与应用[J]. 辽宁化工, 2009, 38( 1) : 38-42. Tian Wei,Bai Fuchen,Li Tianyi. Research progress and application of super absorbent polymer[J]. Liaoning Chemical Industry, 2009, 38( 1) : 38-42. ( in Chinese)
[3]谭凤芝,曹亚峰,李沅. 利用玉米秸秆制备高吸水树脂[J]. 大连工业大学学报, 2009, 28( 5) : 362-365. Tan Fengzhi,Cao Yafeng,Li Yuan. Preparation of superaborbent resin form corn straw[J]. Journal of Dalian Polytechnic University, 2009, 28( 5) : 362-365. ( in Chinese)
[4]王艳. 棉花杆废弃物制备高吸水树脂的研究[J]. 应用化工, 2011, 40( 6) : 997-998.Wang Yan. Study on preparation of superabsorbent resin using cotton straw-discard material[J]. Applied Chemical Industry, 2011, 40( 6) : 997-998. ( in Chinese)
[5]Obert T G,Mercedes M S. Structure and properties of poly( benzyl acrylate) synthesizes under microwave energy[J]. Radiation Physics and Chemistry, 2008, 77( 5) : 597-604.
[6]徐继红,陶俊,谭德新,等. 微波辐射CMC 接枝AA/AMPS 高吸水树脂的制备[J]. 涂料工业, 2011,40( 10) : 30-33. Xu Jihong,Tao Jun,Tan Dexin, et al. Study on synthesis of CMC grafted AA/AMPS super absorben resin by microwave irradiation [J]. Paint and Coatings Industry,2011,40( 10) : 30-33. ( in Chinese)
[7]来水利,韩武军,李斌强. 微波辐射下聚( 丙烯酸-丙烯酰胺) 高吸水性树脂的制备[J]. 精细石油化工,2005,27( 3) : 9- 12. Lai Shuili,Han Wujun,Li Binqiang. Preparation and application of P( AA-AM) super absorbent resin under microwave irradiation [J]. Speciality Petrochemicals,2005, 27 ( 3) : 9-12. ( in Chinese)
[8]秦玉芳,李利,周宁琳. 利用聚乙烯废塑料合成吸水树脂的研究[J]. 南京师大学报: 自然科学版, 2005, 28( 2) : 71-74. Qin Yufang,Li Li,Zhou Ninglin. Synthesis of water-absorbent resin using PE of waste plastic[J]. Journal of Nanjing Normal University: Natural Science Edition,2005, 28( 2) : 71-74. ( in Chinese)
[9]陈日清,蒋煜,储富祥. 反相悬浮聚合法制备耐盐高吸水树脂的研究[J]. 林产化学与工业, 2006, 26( 1) : 28-32. Chen Riqing, Jiang Yu,Chu Fuxiang. Study on preparation and properties of salt-tolerant superabsorbent resin through inversesuspension polymerization[J]. Chemistry and Industry of Forest Products, 2006, 26( 1) : 28-32. ( in Chinese)
[10]常建华. 波谱原理及解析[M]. 2 版. 北京: 科学出版社, 2005. Chang Jianhua. Principle and Analysis of Spectrum[M]. 2nd ed. Beijing: Science Press, 2005. ( in Chinese)
[11]谢侃,陈冬梅,蔡霞. PE 微观结构的红外光谱实用表征[J]. 合成树脂及塑料, 2005, 22( 1) : 48-51. Xie Kan,Chen Dongmei,Cai Xia. Study on the practical characterization of the microstructure of polyethylene by infrared spectroscopy [J]. China Synthetic Resin and Plastics, 2005, 22( 1) : 48-51. ( in Chinese)

备注/Memo

备注/Memo:
基金项目: 江苏省自然科学基金( BK2011838) 、南京信息职业技术学院院级横向科研基金( HX20110047) .通讯联系人: 秦玉芳,讲师,研究方向: 高分子材料. E-mail: qinyf@ njcit. cn
更新日期/Last Update: 2013-03-11