[1]陈 杰,赵雪辉,杜 平,等.高效液相色谱测定J酸及其在废水处理过程中的中控分析[J].南京师范大学学报(工程技术版),2015,15(01):055-59.
　Chen Jie,Zhao Xuehui,Du Ping,et al.Determination of J Acid by High Performance Liquid Chromatographyand Its Middle-Controlled Analysis of Wastewater Treatment[J].Journal of Nanjing Normal University(Engineering and Technology),2015,15(01):055-59.
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高效液相色谱测定J酸及其在废水处理过程中的中控分析
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南京师范大学学报（工程技术版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
15卷
期数:
2015年01期
页码:
055-59
栏目:
化学工程
出版日期:
2015-03-20

文章信息/Info

Title:
Determination of J Acid by High Performance Liquid Chromatographyand Its Middle-Controlled Analysis of Wastewater Treatment
作者:
陈 杰1; 赵雪辉1; 杜 平1; 王玉萍1; 2; 3
(1.南京师范大学化学与材料科学学院,江苏 南京 210097)(2.南京师范大学江苏省物质循环与污染控制重点实验室,江苏 南京 210097)(3.南京理工大学化工污染控制与资源化江苏省高校重点实验室,江苏 南京 210094)
Author(s):
Chen Jie1; Zhao Xuehui1; Du Ping1; Wang Yuping1; 2; 3
(1.School of Chemistry and Materials Science,Nanjing Normal University,Nanjing 210097,China)(2.Jiangsu Key Laboratory of Materials Cycling and Pollution Control,Nanjing Normal University,Nanjing 210097,China)(3.Jiangsu Key Laboratory of Chemical Polluti
关键词:
高效液相色谱; J酸; 中控分析; 萃取
Keywords:
high performance liquid chromatography; J acid; middle-controlled analysis; extraction
分类号:
TQ116.2
文献标志码:
A
摘要:
建立了废水中J酸的高效液相色谱检测方法,并利用所建方法对J酸废水的处理进行控制分析. 采用Krornasil-C18色谱柱分离,流动相为甲醇和水(含4 g/L的四丁基溴化铵)(体积比为35:65),紫外检测波长为230 nm. 结果表明,J酸的浓度在1.06～17.10 mg/L时线性关系良好(r=0.999 6),相对标准偏差为1.03%. 该方法简便快速,结果准确,重现性好,可为J酸废水的处理提供较好的中控分析.
Abstract:
A method for J acid(2-amino-5-naphthol-7-sulfonic acid)in wastewater with high performance liquid chromatography(HPLC)is established. The J acid in wastewater treatment process is analyzed using the established method. HPLC is performed on a Krornasil-C18 column,using methanol and water(containing 4 g/L tetrabutyl ammonium)(35:65)as mobile phase and the detection wavelength of 230 nm. The results show that the calibration curve is linear in the range of 1.06～17.10 mg/L for concentration of J acid(r=0.999 6),precision is high,and its relative standard deviation is 1.92%. The method is rapid,accurate,and reproducible and can be used for quantitative analysis of J acid in wastewater and thus is provided as a good central control analysis method of treatment conditions of wastewater.

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备注/Memo

备注/Memo:
收稿日期:2014-09-17.基金项目:江苏省环保科技专项基金(2013002)、化工污染控制与资源化江苏省高校重点实验室(南京理工大学)创新基金(30920140122008)、江苏省物质循环与污染控制重点实验室,江苏生物医药功能材料协同创新中心,江苏高校优势学科建设工程和南京师范大学光电重点实验室基金资助. 通讯联系人:王玉萍,教授,研究方向:纳米半导体光催化材料及其在环境中的应用. E-mail:wangyuping@njnu.edu.cn
更新日期/Last Update: 2015-03-30