[1]张彤宇,康静静,严乙洋,等.生物炭对水中对乙酰氨基酚的去除性能及机理研究[J].南京师范大学学报(工程技术版),2024,24(01):063-71.[doi:10.3969/j.issn.1672-1292.2024.01.009]
 Zhang Tongyu,Kang Jingjing,Yan Yiyang,et al.Removal of Acetaminophen by Biochar from Aqueous Environment: Performance and Mechanisms[J].Journal of Nanjing Normal University(Engineering and Technology),2024,24(01):063-71.[doi:10.3969/j.issn.1672-1292.2024.01.009]
点击复制

生物炭对水中对乙酰氨基酚的去除性能及机理研究
分享到:

南京师范大学学报(工程技术版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
24卷
期数:
2024年01期
页码:
063-71
栏目:
环境科学与工程
出版日期:
2024-03-15

文章信息/Info

Title:
Removal of Acetaminophen by Biochar from Aqueous Environment: Performance and Mechanisms
文章编号:
1672-1292(2024)01-0063-09
作者:
张彤宇康静静严乙洋王 雨王 号李宵慧陈 晔
(南京师范大学海洋科学与工程学院,江苏 南京 210023)
Author(s):
Zhang TongyuKang JingjingYan YiyangWang YuWang HaoLi XiaohuiChen Ye
(School of Marine Science and Engineering,Nanjing Normal University,Nanjing 210023,China)
关键词:
生物炭对乙酰氨基酚吸附固定床
Keywords:
biocharacetaminophenadsorptionfixed-bed
分类号:
X703
DOI:
10.3969/j.issn.1672-1292.2024.01.009
文献标志码:
A
摘要:
生物炭在水中非甾体类抗炎药(NSAIDs)吸附去除方面具有良好的应用前景. 目前关于生物炭对NSAIDs去除过程和机理的报道较有限,尤其对于动态吸附的研究非常缺乏. 以对乙酰氨基酚为研究对象,分别通过批次吸附实验和固定床吸附实验,研究了商业生物炭对其静态和动态吸附过程. 伪二阶动力学模型和Elovich均能较好地拟合吸附动力学曲线,Langmuir模型对吸附等温线的拟合程度大于Freundlich模型,吸附容量拟合值为131.578 mg/g. 固定床动态吸附实验表明生物炭添加量和流速均可显著影响其动态吸附过程,Thomas模型、Yoon-Nelson模型、Clark模型和BDST模型均可对动态吸附过程进行较好的拟合和预测. 研究表明,生物炭在大规模应用于水中对乙酰氨基酚的去除上具有良好的前景.
Abstract:
Biochar is one of the most promising materials for non-steroidal anti-inflammatory drugs(NSAIDs)removal from aqueous environment. However,the relative study is far from complete and involved mechanisms are unclear,especially about the dynamic adsorption process. Batch adsorption and fixed-bed column experiments are conducted to investigate the removal of acetaminophen(AP)from aqueous environment by commercial biochar. The sorption kinetics are well fitted with Pseudo-second-order model and Elovich model. The adsorption isotherm could be better described by Langmuir model than Freundlich model,and the Langmuir maximum capacity is 131.578 mg/g. Biochar dosage and flow rate affect the dynamic adsorption removal process of fixed-bed columns. Thomas model,Yoon-Nelson model,Clark model and BDST model all well simulate and predict the column experimental data. The results indicate great application prospect of biochar in large-scale AP removal.

参考文献/References:

[1]PEREIRA A,SILVA L,LARANJEIRO C,et al. Selected pharmaceuticals in different aquatic compartments:Part I-source,fate and occurrence[J]. Molecules,2020,25(5):1026.
[2]RASTOGI A,TIWARI M K,GHANGREKAR M M. A review on environmental occurrence,toxicity and microbial degradation of non-steroidal anti-inflammatory drugs(NSAIDs)[J]. Journal of Environmental Management,2021,300:113694.
[3]TYUMINA E A,BAZHUTIN G A,CARTAGENA GóMEZ A D P,et al. Nonsteroidal anti-inflammatory drugs as emerging contaminants[J]. Microbiology,2020,89(2):148-163.
[4]BACSI I,B-BERES V,KOKAI Z,et al. Effects of non-steroidal anti-inflammatory drugs on cyanobacteria and algae in laboratory strains and in natural algal assemblages[J]. Environmental Pollution,2016,212:508-518.
[5]PAWLOWSKA B,TELESINSKI A,BICZAK R. Effect of diclofenac and naproxen and their mixture on spring barley seedlings and Heterocypris incongruens[J]. Environmental Toxicology Pharmacology,2021,88:103746.
[6]SIEMIENIUK A,LUDYNIA M,RUDNICKA M. Response of two crop plants,Zea mays L. and Solanum lycopersicum L.,to diclofenac and naproxen[J]. International Journal of Molecular Sciences,2021,22(16):8856.
[7]卜庆伟,张鑫,余刚. 吸附法去除水中典型药物及个人护理品的研究进展[J]. 环境工程,2021,39(2):1-9.
[8]AKHTAR J,AMIN N A S,SHAHZAD K. A review on removal of pharmaceuticals from water by adsorption[J]. Desalination and Water Treatment:Science and Engineering,2015,57(27):12842-12860.
[9]PRIYA A K,GNANASEKARAN L,RAJENDRAN S,et al. Occurrences and removal of pharmaceutical and personal care products from aquatic systems using advanced treatment-A review[J]. Environmental Research,2022,204:112298.
[10]OBA S N,IGHALOA J O,ANIAGOR C O,et al. Removal of ibuprofen from aqueous media by adsorption:A comprehensive review[J]. Science of the Total Environment,2021,780:146608.
[11]DU Y D,ZHANG X Q,SHU L,et al. Safety evaluation and ibuprofen removal via an Alternanthera philoxeroides-based biochar[J]. Environmental Science and Pollution Research,2021,28(30):40568-40586.
[12]ZHANG M,SHEN J L,ZHONG Y C,et al. Sorption of pharmaceuticals and personal care products(PPCPs)from water and wastewater by carbonaceous materials:A review[J]. Critical Reviews in Environmental Science and Technology,2022,52(1-6):727-766.
[13]吴阳,刘振中,江文,等. 生物炭对几类常见新兴污染物去除的研究进展[J]. 化工进展,2021,40(5):2839-2851.
[14]SHAHRAKI Z M,MAO X W. Biochar application in biofiltration systems to remove nutrients,pathogens,and pharmaceutical and personal care products from wastewater[J]. Journal of Environmental Quality,2022,51(2):129-151.
[15]ANFAR Z,ZBAIR M,AIT AHSIANE H,et al. Microwave assisted green synthesis of Fe2O3/biochar for ultrasonic removal of nonsteroidal anti-inflammatory pharmaceuticals[J]. RSC Advance,2020,10:11371-11380.
[16]LUO R,LI X H,XU H X,et al. Effects of temperature,solution pH,and ball-milling modification on the adsorption of non-steroidal anti-inflammatory drugs onto biochar[J]. Bulletin of Environmental Contamination and Toxicology,2020,105(3):422-427.
[17]NAIMA A,AMMAR F,ABDELKADER O,et al. Development of a novel and efficient biochar produced from pepper stem for effective ibuprofen removal[J]. Bioresource Technology,2022,347:126685.
[18]SUMALINOG D A G,CAPAREDA S C,DE LUNA M D G. Evaluation of the effectiveness and mechanisms of acetaminophen and methylene blue dye adsorption on activated biochar derived from municipal solid wastes[J]. Journal of Environmental Management,2018,210:255-262.
[19]PATEL M,KUMAR R,PITTMAN J C U,et al. Ciprofloxacin and acetaminophen sorption onto banana peel biochars:Environmental and process parameter influences[J]. Environmental Research,2021,201:111218.
[20]ZHENG Y L,WANG B,WESTER A E,et al. Reclaiming phosphorus from secondary treated municipal wastewater with engineered biochar[J]. Chemical Engineering Journal,2019,362:460-468.
[21]吴伟健,陈艺杰,李高洋,等. 水稻秸秆生物炭对镉污染农田中番茄产量和品质的影响机制[J]. 农业环境科学学报,2022,41(3):492-503.
[22]刘总堂,邵江,李艳,等. 碱改性小麦秸秆生物炭对水中四环素的吸附性能[J]. 中国环境科学,2022,42(8):3736-3743.
[23]商岑尧,顾若婷,张强,等. 秸秆生物炭吸附对乙酰氨基酚的机制及其位能分布特征[J]. 环境科学,2022,43(9):4888-4901.
[24]CHEN D,WANG X B,WANG X L,et al. The mechanism of cadmium sorption by sulphur-modified wheat straw biochar and its application cadmium-contaminated soil[J]. Science of the Total Environmental,2020,714:136550.
[25]单锐,谈莉,陈凤鸣,等. 改性山竹壳炭对废水中Ni(Ⅱ)的吸附效果与机理研究[J]. 安全与环境学报,2022,22(6):3473-3483.
[26]CHAKRABORTY P,BANERJEE S,KUMAR S,et al. Elucidation of ibuprofen uptake capability of raw and steam activated biochar of Aegle marmelos shell:Isotherm,kinetics,thermodynamics and cost estimation[J]. Process Safety and Environmental Protection,2018,118:10-23.
[27]陈天涯,袁木子,张舒羽,等. 老化秸秆生物炭对诺氟沙星吸附特性的研究[J]. 农业环境科学学报,2022,41(5):1047-1057.
[28]宋豆豆,李莉,刘伟婷. 玉米秸秆改性生物炭对磺胺类抗生素的吸附特性[J]. 生态与农村环境学报,2021,37(11):1473-1480.
[29]LIU L,LIU Y J. Biosorption isotherms,kinetics and thermodynamics[J]. Separation and Purification Technology,2008,61(3):229-242.
[30]孔郑磊,李晓晨,杨继利,等. 改性荔枝皮对水中Pb(Ⅱ)的动态吸附特性[J]. 环境科学研究,2014,27(10):1186-1192.
[31]FAN Z X,ZHANG Q,GAO B,et al. Removal of hexavalent chromium by biochar supported nZVI composite:Batch and fixed-bed column evaluations,mechanisms,and secondary contamination prevention[J]. Chemosphere:Environmental Toxicology and Risk Assessment,2019,217:85-94.
[32]DALHAT M A,MU'AZU N D,Essa M H. Generalized decay and artificial neural network models for fixed-Bed phenolic compounds adsorption onto activated date palm biochar[J]. Journal of Environmental Chemical Engineering,2021,9:104711.
[33]DAS L,SENGUPTA S,DAS P,et al. Experimental and numerical modeling on dye adsorption using pyrolyzed mesoporous biochar in batch and fixed-bed column reactor:Isotherm,thermodynamics,mass transfer,kinetic analysis[J]. Surfaces and Interfaces,2021,23:100985.
[34]ZHANG Y P,YUE X P,XU W W,et al. Amino modification of rice straw-derived biochar for enhancing its cadmium(II)ions adsorption from water[J]. Journal of Hazardous Materials,2019,379:120783.
[35]KUNDU S,GUPTA A K. As(III)removal from aqueous medium in fixed bed using iron oxide-coated cement(IOCC):Experimental and modeling studies[J]. Chemical Engineering Journal,2007,129(1-3):123-131.
[36]DONG S A,SUN YY,WU J C,et al. Graphene oxide as filter media to remove levofloxacin and lead from aqueous solution[J]. Chemosphere,2016,150:759-764.

备注/Memo

备注/Memo:
收稿日期:2023-03-01.
基金项目:国家自然科学基金项目(42107061)、江苏省自然科学基金项目(BK20210571)、江苏省高校自然科学基金项目(21KJB170023)、南京师范大学海洋科学与工程学院大学生创新创业计划项目.
通讯作者:李宵慧,博士,副教授,研究方向:污染物迁移、转化及修复. E-mail:xhli@njnu.edu.cn
更新日期/Last Update: 2024-03-15