|Table of Contents|

Structural and Charge Parameters of Spiral Nanofiltration Membrane(PDF)

南京师范大学学报(工程技术版)[ISSN:1006-6977/CN:61-1281/TN]

Issue:
2008年02期
Page:
46-50
Research Field:
Publishing date:

Info

Title:
Structural and Charge Parameters of Spiral Nanofiltration Membrane
Author(s):
Zhang Xianqiu1Xue Liping2Du Mingxia1Wang Liyou1Pan Fei1
1.School of Power Engineering,Nanjing Normal Universty,Nanjing 210042,China;2.Environment School,Anhui Universty of Architecture,Hefei 230022,China
Keywords:
nanofiltra tion m em brane SHP m ode l TM S m ode l struc tura l param eters charge character ization
PACS:
TB383.2
DOI:
-
Abstract:
S tructura l param e ters( m embrane pore rad ius and the ratio o fm em brane poro sity tom em brane thickness) and the param eters o f charge characterstics ( Charge density ) are the m ost im portant characteristic param eters of nano filtration m em brane, and are a lso key fac to rs wh ich have an im po rtant influence on separation pe rfo rm ance. Perm eation experim ents o f aqueous solution of neutra l so lutes and electro ly tew ith NF90 and NF270 spiralm embranes w ere conducted and m em branes param e ters ( reflec tion coeffic ient and so lute pe rm eab ility) w ere obtained from Spieg ler-Kedem equation, then structura l param eters and the effective charge densities w ere estim a ted using the ster ic-h indrance pore ( SH P) model and TM S m ode l respectiv ely. M em brane po re radius o fNF90 and NF270 w ere about 0.46 nm and 0.60 nm respective ly, the ra tio of membrane po rosity to m em brane th ickness w ere about 0.99× 105 m - 1 and 1.14 × 105 m - 1 respective ly, Charge density cou ld be determ ined byX ( NF90) = 54.89Cm + 175.85 and X ( NF270) = 6.20Cm + 6.55 respectively.

References:

[ 1] 王晓琳, 中尾真一. 低分子量中性溶质体系纳滤膜的透过特性[ J]. 南京化工大学学报, 1998, 20( 4): 36-40.
W ang X iao lin, N akao S. Perm eation perform ance of nano filtration m em branes for system s of aqueous so lutions o f neutra l so lu tes w ith low mo lecu la rw eigh t[ J]. Jou rnal of NanjingUn ive rsty of Chem ical Techno logy, 1998, 20( 4): 36-40. ( in Chinese)
[ 2] W ang X L, Tsuru T, N akao S, e t a.l E lectro ly te transport through nano filtration membrane by the space-cha rgem odel and the compar ison w ith Teo re l-lM eyer-S iev ers m ode l [ J]. Journal ofM embrane Science, 1995, 103: 117-133.
[ 3] W ang X L, Tsuru T, N akao S, et a .l The electrostatic and ster ic-h indrance mode l for the transpo rt o f charged so lutes through nano filtration m embrane [ J]. Journal o fM embrane Science, 1997, 135( 1) : 19-32.
[ 4] Bow enW R, M ohamm ed A W. D iafiltration by nano filtration-pred iction and optim iza tion[ J] . A IChE, 1998, 44( 8): 1 799-1 812.
[ 5] Bandin i S, Vezzan iD. Nano filtration m ode ling: the role of dielectr ic exc lusion in m embrane character ization[ J]. Chem ical  Eng ineer ing Sc ience, 2003, 58( 15): 3 303-3 326.
[ 6] Isma ilA F, H assan A R. The deduc tion of fine structural deta ils of asymm etr ic nanofiltration m embranes us ing theoretica lmodels[ J]. Journa l o fM em brane Sc ience, 2004, 231( 1 /2): 25-36.
[ 7] W ang K Y, Chung T S. The characteriza tion o f fla t composite nano filtration m embranes and the ir applications in the separation o f cephalex in[ J] . Journa l ofM embrane Sc ience, 2005, 247( 1 /2): 37-50.
[ 8] Spieg lerK S, Kedem. Therm odynam ic o f hype rfiltration( reverse osm osis): cr iteria fo r effic ient m embranes[ J]. Desa lina tion,1966, 1: 311-326.
[ 9] Schock G, M ique lA. M ass transfer and pressure loss in spiral wound m odules[ J] . Desa lination, 1987, 64: 339-352.
[ 10] Bow enW R, M ohamm ad A W, H ilaln. Cha racte rization of nano filtration membrane for predictive purposes: use of sa lts, uncharged solutes and atom ic fo rce m icroscopy[ J]. Journa l o fM em brane Sc ience, 1997, 126( 1): 91-105.
[ 11] 张显球, 张林生, 吕锡武. 纳滤软化除盐效果的研究[ J]. 水处理技术, 2004, 30( 6) : 352-354.
Zhang X ianqiu, Zhang Linsheng, L  X iw u. The study on w ater soften ing by nano filtration[ J]. W a terTreatm ent Techno logy,2004, 30( 6) : 352-354. ( in Ch inese)
[ 12] 张显球, 张林生, 吕锡武. 纳滤处理C r[   ]废水的试验研究[ J]. 环境污染治理技术与设备, 2005, 6( 3): 25-27.
Zhang Xianqiu, Zhang L insheng, L X iw u. The experim ents on hex ava lent chrom ium w astew ater by nano filtration[ J]. Techniques and Equ ipm en t for Env ironm enta l Pollution Contro,l 2005, 6( 3): 25-27. ( in Ch inese)
[ 13] 张国亮. 高硬度水质下纳滤系统的运行状态及分析[ J]. 膜科学与技术, 2000, 20( 2): 43-48.
Zhang Guoliang. Stud ies on ope ra ting charac teristics o f NF sy stem in h igh hardness wa ter treatm ent[ J]. M em brane Science and Techno logy, 2000, 20( 2): 43-48. ( in Ch inese)
[ 14] 张显球. 纳滤模型优化及水处理应用研究[ D]. 南京: 东南大学, 2007.
Zhang Xianq iu. M ode l optim ization o f nanofiltra tion and its app lication in water trea tm en t[ D]. Nanjing: SoutheastUn iversty,2007. ( in Ch inese)

Memo

Memo:
-
Last Update: 2013-04-24