[1]卜洪忠,高旭昇,姚成.三苯基銚鏻盐的合成及其杀菌性能评定[J].南京师范大学学报(工程技术版),2005,05(02):061-63.
　BU Hongzhong,GAO Xusheng,YAO Cheng.Synthesis of Triphenyl Phosphonium Salts and their Bactericidal Properties[J].Journal of Nanjing Normal University(Engineering and Technology),2005,05(02):061-63.
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三苯基銚鏻盐的合成及其杀菌性能评定
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南京师范大学学报（工程技术版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
05卷
期数:
2005年02期
页码:
061-63
栏目:
出版日期:
2005-06-30

文章信息/Info

Title:
Synthesis of Triphenyl Phosphonium Salts and their Bactericidal Properties
作者:
卜洪忠; 高旭昇; 姚成
南京工业大学理学院, 江苏南京210009
Author(s):
BU Hongzhong;  GAO Xusheng;  YAO Cheng
School of Sciences, Nanjing University of Technology,Jiangsu Nanjing 210009, China
关键词:
十二烷基三苯基氯化鏻(DTPPC);  十二烷基三苯基溴化鏻(DTPPB);  合成;  杀菌性能
Keywords:
dodecy ltripheny l pho sphon ium ch lo ride ( DTPPC );  dodecy ltr ipheny l phosphonium brom ide ( DTPPB );  synthesis;  bacte ricida l prope rty
分类号:
TQ455.4
摘要:
以1氯代十二烷、1溴代十二烷和三苯基膦为原料合成了三苯基盐产品十二烷基三苯基氯化(DTPPC)和十烷基三苯基溴化(DTPPB),产率分别为61.4%和70.9%,并进行了红外光谱分析和元素分析鉴定.用磷钼酸喹啉容量法对产品进行了测定,DTPPC和DTPPB的百分含量分别为98.94%和98.83%.杀菌性能评定的结果表明:当DTPPC和DTPPB的浓度均为50ug/mL时,对硫酸盐还原菌的杀菌率分别为100%和99.9%;当DTPPC和DTPPB的浓度均为100ug/mL时,对异养菌的杀菌率分别为99.8%和99.7%.产品对硫酸盐具有良好的杀菌效果.
Abstract:
Two substances-dodecy l triphenyl pho sphon ium ch lor ide( DTPPC) and dodecyl tripheny l phosphonium brom ide( DTPPB) are respective ly synthesized from 1-dodecane chlor ide, 1-dodecane brom ide and tr ipheny l phosphon-i um w ith the y ie lds of 61. 4% and 70. 9%. The ir struc tures are identified by IR and elem ent ana lysis. The tw o chem -i cals are iden tified by volum etr ic m ethod of qu ino line phosphom o lybdate, and the contents o f DTPPC and DTPPB are 98. 94% and 98. 83% respective ly. Test o f the ir bacteric idal prope rties show s that bacteric idal effic iencies on sulfatereduc ing bac teria( SRB) are 100% and 99. 9% respective ly when the concentra tion is 50ug /mL and they are 99. 8% and 99. 7% on heterotroph ic bacter ia ( HB ) respective ly when it is 100 Lg /mL. DTPPC and DTPPB are effec tive bacter icides on SRB.

参考文献/References:

[ 1] 李本高. 循环冷却水用杀生剂季盐[ J]. 石油炼制, 1993, 24( 12): 53- 57.
[ 2] Kurt M oedr itze r, W ebster G roves. Antiseptic de tergent com positions[ P]. US Patent: 3281365, 1966-10-25.
[ 3] K anazawa, Ikeda, Endo. Po lym eric pho sphon ium sa lts as a nove l class o f ca tionic bioc ides. V. syn thesis and ant-i bacter ial activ ity o f po ly esters releasing phosphonium bioc ides[ J]. J Po lym Sc i ( Part A: Polym Chem ), 1993, 31 ( 12): 3003- 3011.
[ 4] 姚成, 卜洪忠, 王小康, 等. 杀菌剂DTPC 和TTPC 的合成及应用研究[ J]. 工业水处理, 1999, 19 ( 3): 16- 18.
[ 5] 杨光, 曾昭琼. 几种Ph3 P+ RX - 型季盐的合成[ J]. 化学试剂, 1992, 14( 6): 344 -345.
[ 6] 姚成, 卜洪忠, 徐丽娜, 等. 季盐三丁基十四烷基氯化( TTPC)的测定[ J]. 工业水处理, 1999, 19( 4) : 34- 35.

备注/Memo

备注/Memo:
作者简介: 卜洪忠( 1968-) , 讲师, 主要从事分析和精细合成的教学与研究. E-m a il:n jbhz@ s ina. com
更新日期/Last Update: 2013-04-29