[1]顾正桂,职慧珍,毛梅芳,等.连续反应精制二乙氧基甲烷[J].南京师范大学学报(工程技术版),2004,04(02):008-10.
　GU Zhenggui,ZHI Huizhen,MAO Meifang,et al.Study on DEM Synthesis by Continuous Reaction Distillation[J].Journal of Nanjing Normal University(Engineering and Technology),2004,04(02):008-10.
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连续反应精制二乙氧基甲烷
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南京师范大学学报（工程技术版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
04卷
期数:
2004年02期
页码:
008-10
栏目:
出版日期:
2004-06-30

文章信息/Info

Title:
Study on DEM Synthesis by Continuous Reaction Distillation
作者:
顾正桂; 职慧珍; 毛梅芳; 林军
南京师范大学化学与环境科学学院, 江苏南京210097
Author(s):
GU Zhenggui;  ZHI Huizhen;  MAO Meifang;  LIN Jun
School of Chemistry and Environmental Science,Nanjing Normal University, Nanjing 210097, China
关键词:
二乙氧基甲烷;  催化剂;  反应时间;  搅拌速度;  反应温度;  原料配比;  合成
Keywords:
DEM;  Catalyst;  Reaction time;  Material ratio;  Synthesis
分类号:
TQ22
摘要:
在前人研究的基础上 ,提出以乙醇、甲醛为原料 ,采用固体酸 (苯磺酸 )作催化剂 ,研究各种因素对合成二乙氧基甲烷反应过程的影响 ,在催化剂用量、原料配比、反应时间、搅拌速度一定的条件下 ,首先考察反应温度对合成过程的影响 ,选择适宜的反应温度 ;其次考察其它因素对反应过程的影响 ,通过研究确定二乙氧基甲烷合成过程的工艺参数 ;在其它条件不变的情况下 ,与浓盐酸催化法进行比较 ;通过系统的研究为进一步研究和工业化试验提供条件 .
Abstract:
A new method for diethoxymethane synthesis using ethanol and formaldehyde as raw material and a solid acid ( benzene sulfonic acid) as catalyst was studied. Different effects on the synthesis process were discussed in detail. The influence of temperature on the process of the synthesis was considered primarily at fixed catalyst amount, raw material ratio, reaction time and stirring time to optimize the temperature for the reaction. The effects of other factors on the synthesis process were then also considered to optimize the process parameters. The method was also compared with that using chlorhydric acid as catalyst. The results were of some value for further research and industrialization.

参考文献/References:

[ 1] 章思规. 精细有机化学品技术手册( 上) [M] . 北京: 科学出版社, 1991. 678.
[ 2] Jones R V H, Bloomer J M. Process for the preparation of aryl and aralkyl magnesium halides [ P] . 世界专利: WO 9302086, 1993- 02- 06.
[ 3] Mukoyama M, Yorozu K, Takai T, et al . Method for preparation of expoxy and alpha-hydroxy Carbonyl compounds from Olefins[ P] . 日本专利: JP 06166651, 1994- 06- 01.
[ 4] Ito A, Yoshida M, Nakase Y, et al. Poly ( oxymethylene ) having good thermal stability [ P] . 德国专利: DE 2001396, 1970- 03- 16.
[ 5] 张士英, 吴达俊. 二乙氧基甲烷的制备和应用[ J] . 合成化学, 1997, 5( 4) : 344- 356.
[ 6] 顾正桂, 毛梅芳, 林军, 等. 二乙氧基甲烷与乙醇水溶液的液液萃取模拟计算[ J] . 计算机与应用化学, 2003, 20 ( 1) : 40- 44.
[ 7] 顾正桂, 职慧珍, 毛梅芳, 等. 乙醇水溶液与二乙氧基甲烷的萃取分离[ J] . 化学研究与应用, 2003, 20( 1) : 550- 554.
[ 8] 卢焕章. 石油化工基础数据手册[M] . 北京: 化学工程出版社, 1992.
[ 9] 顾正桂, 毛梅芳, 林军. 二乙氧基甲烷与乙醇水溶液的液液萃取[ P] . 中国专利: CN 1388107A, 2003- 01- 23.

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备注/Memo

备注/Memo:
作者简介: 顾正桂( 1962- ) , 硕士, 副教授, 香港远程教育学院终身教授, 主要从事化工分离及工艺的教学与研究. E-mail: zggu@ 263. net
更新日期/Last Update: 2013-04-29