[1]黄东平,顾慧丹,张叶,等.双酚A双(二苯基磷酸酯)阻燃剂的合成[J].南京师范大学学报(工程技术版),2006,06(04):030-33.
　HUANG Dongping,GU Huidan,ZHANG Ye,et al.Synthesis of Bisphenol-A Bis(Diphenyl Phosphate) Flame Retardant[J].Journal of Nanjing Normal University(Engineering and Technology),2006,06(04):030-33.
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双酚A双(二苯基磷酸酯)阻燃剂的合成
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南京师范大学学报（工程技术版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
06卷
期数:
2006年04期
页码:
030-33
栏目:
出版日期:
2006-12-30

文章信息/Info

Title:
Synthesis of Bisphenol-A Bis(Diphenyl Phosphate) Flame Retardant
作者:
黄东平;顾慧丹;张叶;杨锦飞;
南京师范大学化学与环境科学学院,江苏南京210097
Author(s):
HUANG Dongping; GU Huidan; ZHANG Ye; YANG Jinfei
School of Chemistry and Environmental Science,Nanjing Normal University,Nanjing 210097,China
关键词:
双酚A;  双酚A双(二苯基磷酸酯);  阻燃剂;  合成
Keywords:
bisphenol-A;  bisphenol-A bis ( diphenyl phosphate) ;  flame retardant;  synthesis
分类号:
TQ314.248
摘要:
用三氯氧磷、双酚A与苯酚反应制得化合物双酚A双(二苯基磷酸酯).采用单因素法分别对物料比、反应温度、催化剂进行讨论,确定了适宜的工艺条件:三氯氧磷、双酚A与苯酚的物质的量之比为3∶1∶4.05;第一步反应温度为50℃,反应时间为6 h;第二步反应温度为140℃,反应时间为8 h;以A lC l3为催化剂,用量为双酚A总质量的2%,产品收率达88.7%.通过FT-IR对化合物的结构进行了表征,产品质量达到国外同类产品指标.在塑料中对其阻燃性能做了测试,结果表明它是一种较好的阻燃剂.
Abstract:
Bisphenol-A bis ( diphenyl phosphate) was synthesized from phosphorus oxychloride bisphenol-A and phe-nol. The effects of p rocess parameters, such asmolar ratio, reaction temperature and catalyst on the yield were stud ied respectively, the suitable synthesis conditionswere defined as follows: the molar ratio of phosphorus oxychloride, bisphenol-A and phenol: 3∶1∶4.05. In the firs step, the reaction temperature was 50℃, and the reaction time was 6 hours. In the second step, the reaction temperature was 140℃, and the reaction time was 8 hours. AlCl3 was the best catalyst, and its dosage was 2% of the amount of all bisphenol2A. The yield reached 88.7%. The structure of the p roduct was defined by FT2IR. The quality of the p roduct can reach the indexes of the oversea p roduct. The flame re tardance was tested in different p lastic p roduct, which showed that the bisphenol-A bis ( diphenyl phosphate) was a good flame retardant.

参考文献/References:

[ 1 ] 王新龙,朱绪光,宋晔,等. 双酚A磷酸酯齐聚物阻燃剂的合成研究[ J ]. 精细石油化工进展, 2001, 2 (5) : 11-13.
WANG Xinlong, ZHU Xuguang, SONG Yi, et al. Study on synthesis of bisphenol A phosphate oligomers as flame retardant [ J ]. Advances in Fine Petrochemicals, 2001, 2 (5) : 11-13. ( in Chinese)
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备注/Memo

备注/Memo:
作者简介: 黄东平(19802) ,硕士研究生,主要从事有机合成和阻燃剂等方面的学习与研究. E-mail: hdongp ing1224@126. com
通讯联系人:杨锦飞(19562) ,教授,主要从事阻燃剂及药物中间体的合成与应用的教学与研究.E-mail: yangjinfei@njnu. edu. cn
更新日期/Last Update: 2013-04-29