[1]杨志琴,贾峰,刘荣,等.费托合成催化剂的研究进展[J].南京师范大学学报(工程技术版),2011,11(02):062-67.
 Yang Zhiqin,Jia Feng,Liu Rong.The Advances of Catalysts for Fischer-Tropsch Synthesis[J].Journal of Nanjing Normal University(Engineering and Technology),2011,11(02):062-67.
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费托合成催化剂的研究进展
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南京师范大学学报(工程技术版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
11卷
期数:
2011年02期
页码:
062-67
栏目:
出版日期:
2011-04-09

文章信息/Info

Title:
The Advances of Catalysts for Fischer-Tropsch Synthesis
作者:
杨志琴;贾峰;刘荣;
南京师范大学地理科学学院,江苏南京210046
Author(s):
Yang ZhiqinJia FengLiu Rong
School of Geography Science,Nanjing Normal University,Nanjing 210046,China
关键词:
费托合成氧化锆催化剂
Keywords:
Fischer-Tropsch synthesisZirconiacatalysts
分类号:
TQ529.2;TQ426.94
摘要:
费托合成反应是将生物质转化成生物质液体燃料的技术核心,其关键是开发活性高、选择性高和稳定性好的催化剂.分析总结了近几年费托合成催化剂的分类体系、组成特点和发展状况,着重介绍了氧化锆在费托合成催化剂中的应用现状,分析发现ZrO2可以显著改善费托合成催化剂的性能.
Abstract:
Fischer-Tropsch synthesis reaction is the technology core for biomass into liquid fuels. The key factors in this process are the activity and selectivity for catalyst. In this paper,the characteristics and development of catalysts are reviewed, and then the application of Zirconia in Fischer-Tropsch synthesis are introduced. It is found that ZrO2 can significantly improve the performance of catalysts for Fischer-Tropsch synthesis.

参考文献/References:

[1]苏海全,张晓红,丁宁,等. 费托合成催化剂的研究进展[J]. 内蒙古大学学报: 自然科学版,2009,40( 4) : 409-513. Su Haiquan,Zhang Xiaohong,Ding Ning,et al. Research progress of Fischer-Tropsch synthesis catalysts[J]. Journal of Inner Mongolia University: Natural Science Edition,2009,40( 4) : 409-513. ( in Chinese)
[2]Pham H N,Datye A K. The synthesis of attrition resistant slurry phase iron,Fischer-Tropsch catalysts[J]. Catalysis Today, 2000,58( 4) : 233-240.
[3]Hoc W N,Zhang Yongqing,O’Brien R J,et al. Fischer-Tropsch syntheses: Activity and selectivity for group I alkali promoted iron-based catalysts[J]. Applied Catalysis A: General,2002,236( 1 /2) : 77-89.
[4]张成华,杨勇,陶智超,等. Cu、K 助剂对FeMn /SiO2 催化费托合成的影响[J]. 物理化学学报,2006,22( 11) : 1 310- 1 316. Zhang Chenghua,Yang Yong,Tao Zhichao,et al. Effects of Cu and K on Co-precipitated FeMn /SiO2 catalysts for Fischer- Tropsch synthesis[J]. Acta Physico-Chimica Sinica,2006,22( 11) : 1 310-1 316. ( in Chinese)
[5]石玉林,吕毅军,王鹏,等. 神华低温浆态床费托合成铁系催化剂的研究开发[J]. 石油学报( 石油加工) ,2010,10: 240-245. Shi Yulin,Lü Yijun,Wang Peng,et al. Catalyst research and development for low temperature slurry Fischer-Tropsch synthesis [J]. Acta Petrolei Sinica ( Petroleum Processing Section) ,2010,10: 240-245. ( in Chinese)
[6]Bezemer G Leendert,Bitter Johannes H,Kuipers Herman P C E,et al. Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts[J]. Journal of the American Chemical Society,2006,128 ( 1 /2) : 3956-3964.
[7]张辉,储伟. 贵金属助剂对费-托合成用钴基催化剂的促进作用[J]. 化学进展,2009,21( 4) : 622-628. Zhang Hui,Chu Wei. Effects of noble metal promoters on supported Cobalt-based Fischer-Tropsch catalysts[J]. Progress in Chemistry,2009,21( 4) : 622-628. ( in Chinese)
[8]张俊岭,陈建刚,任杰,等. 钴基F-T 合成重质烃催化剂载体效应的研究[J]. 催化学报,2001,22( 3) : 275-278. Zhang Junling,Chen Jiangang,Ren Jie,et al. Role of supports in Cobalt-based catalysts for Fischer-Tropsch synthesis of heavy hydrocarbons[J]. Chinese Journal of Catalysis,2001,22( 3) : 275-278. ( in Chinese)
[9]贾利宏,贾丽涛,李德宝,等. 硅烷化对SBA-15 负载钴催化剂的费-托合成反应性能的影响[J]. 天然气化工,2010, 35( 4) : 6-11. Jia Lihong,Jia Litao,Li Debao,et al. Effect of silylation of SBA-15 supported cobalt catalysts on their performances in Fischer- Tropsch synthesis[J]. Natural Gas Chemical Industry,2010,35( 4) : 6-11. ( in Chinese)
[10]Enache Dan I,Roy-Auberger Magalie,Revel Renaud. Differences in the characteristics and catalytic properties of cobaltbased Fischer-Tropsch catalysts supported on Zirconia and Alumina[J]. Applied Catalysis A: General,2004,268 ( 1 /2) : 51-60.
[11]赵红霞,陈建刚,孙予罕. 载体焙烧温度对Co /ZrO2 催化剂催化F-T 合成反应的影响[J]. 催化学报,2003,24( 12) : 933-936. Zhao Hongxia,Chen Jiangang,Sun Yuhan. Effect of calcination temperature of support on catalytic performance of Co /ZrO2 for Fischer-Tropsch synthesis[J]. Chinese Journal of Catalysis,2003,24( 12) : 933-936. ( in Chinese)
[12]马中义,杨成,董庆年,等. 不同形态ZrO2 负载Co 催化剂上CO + H2 吸附与反应行为研究[J]. 高等学校化学学报, 2005,26( 5) : 902-906. Ma Zhongyi,Yang Cheng,Dong Qingnian,et al. Adsorption and reaction behavior over Co catalysts supported by different Zirconia Polymorphs[J]. Chemical Journal of Chinese Universities,2005,26( 5) : 902-906. ( in Chinese)
[13]李金林,刘行宇. 高比表面积ZrO2 负载的钴基费-托合成催化剂结构和催化性能[J]. 中南民族大学学报: 自然科学版,2010,29( 2) : 1-5. Li Jinlin,Liu Xingyu. Studies on the structure and catalytic property of high surface area Zizconia supported Cobalt Fischer- Tropsch synthesis catalysts[J]. Journal of South Central University for Nationalities: Natural Science Edition,2010,29( 2) : 1-5. ( in Chinese)
[14]Liu Yachun,Fu Zaihui,Jia Litao,et al. Improvement of yield of clean dieael oil from mesoporous Zirconia supported Cobalt catalyst for Fischer-Tropsch synthesis[J]. Journal of Natural Science of Hunan Normal University,2010,33( 2) : 68-71.
[15]Jongsomjit Bunjerd,Panpranot Joongjai,Goodwin James G Jr. Effect of Zirconia-modified alumina on the properties of Co /γ- Al2O3 catalysts[J]. Journal of Catalysis,2003,215( 1) : 66-77.
[16]Rohr F,Lindvag O A,Holmen A,et al. Fischer-Tropsch synthesis over Cobalt supported on Zirconia-modified alumina[J]. Catalysis Today,2000,58( 4) : 247-254.
[17]李强,徐继鹏,代小平,等. 助剂锆对费托合成反应性能的影响[J]. 石油与天然气化工,2003,32( 2) : 71-74. Li Qiang,Xu Jipeng,Dai Xiaoping,et al. Effect of ZrO2 loadings on catalytic performance of Co /SiO2 for F-T synthesis[J]. Chemical Engineering of Oil & GAS,2003,32( 2) : 71-74. ( in Chinese)
[18]王涛,丁云杰,熊建民,等. Zr 助剂对Co /AC 催化剂催化费-托合成反应性能的影响[J]. 催化学报,2005,26( 3) : 178-182. Wang Tao,Ding Yunjie,Xiong Jianmin,et al. Effect of Zr promoter on catalytic performance of Co /AC catalyst for F-T synthesis [J]. Chinese Journal of Catalysis,2005,26( 3) : 178-182. ( in Chinese)
[19]Chang Jie,Chen Jiangang,Teng Botao,et al. Effect of ZrO2 promoter on structural change of Co /SiO2 catalyst during its deactivation in F-T synthesis[J]. Chinese Journal of Catalysis,2005,26( 9) : 731-733.

备注/Memo

备注/Memo:
基金项目: 江苏省教育厅基金( 2008112TSJ0125) .通讯联系人: 刘荣,博士,副教授,研究方向: 材料制备及加工工艺. E-mail: liurongle@163. Com
更新日期/Last Update: 2013-03-21