[1]罗轩,史红丽,杨锦飞,等.水相中合成磷酸三苯酯的研究[J].南京师范大学学报(工程技术版),2012,12(01):085-87.
 Luo Xuan,Shi Hongli,Yang Jinfei,et al.Study on Synthesis of Triphenyl Phosphate in Water[J].Journal of Nanjing Normal University(Engineering and Technology),2012,12(01):085-87.
点击复制

水相中合成磷酸三苯酯的研究
分享到:

南京师范大学学报(工程技术版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
12卷
期数:
2012年01期
页码:
085-87
栏目:
出版日期:
2012-03-20

文章信息/Info

Title:
Study on Synthesis of Triphenyl Phosphate in Water
作者:
罗轩;史红丽;杨锦飞;职慧珍;
南京师范大学化学与材料科学学院,江苏南京210097
Author(s):
Luo XuanShi HongliYang JinfeiZhi Huizhen
School of Chemistry and Materials Science,Nanjing Normal University,Nanjing 210097,China
关键词:
水相磷酸三苯酯合成
Keywords:
watertriphenyl phosphatesynthesis
分类号:
TQ414
摘要:
研究了在水相中合成磷酸三苯酯的工艺条件,找到了一条比较好的易实现工业化的合成方法,完全用水作溶剂,当n(PhOH)∶n(NaOH)∶n(POCl3)=0.90∶0.99∶0.33,反应时间为2.5 h时,可使产率达到91%.
Abstract:
The technological conditions of synthesis of triphenyl phosphate in water at room temperature were studied, and a better and easily industrialized process was found. When the reaction time is 2. 5 h and n( PhOH) ∶ n( NaOH) ∶ n ( POCl3 ) = 0. 90∶ 0. 99∶ 0. 33,91% yield can be obtained.

参考文献/References:

[1]李朝军,陈德恒,王东. 水相有机反应大全[M]. 北京: 科学出版社, 2009. Li Chaojun,Chen Deheng,Wang Dong. Comprehensive Organic Reaction in Aqueous Media[M]. Beijing: Science Press, 2009. ( in Chinese)
[2]Butler Richard N,Coyne Anthony G. Water: nature’s reaction enforcer———comparative effects for organic synthesis“in-water” and“on-water”[J]. Chemical Review,2010,110( 10) : 6 302-6 337.
[3]Mondal Jahur A,Nihonyanagi Satoshi,Yamaguchi Shoichi,et al. Structure and orientation of water at charged liquid monolayer /water interfaces probed by heterodyne-detected vibrational sum frequency generation spectroscopy[J]. Journal of the American Chemical Society,2010,132( 31) : 10 656-10 657.
[4]Fenn Emily E,Moilanen David E,Levinger Nancy E,et al. Fayer water dynamics and interactions in water-polyether binary mixtures[J]. Journal of the American Chemical Society,2009,131( 15) : 5 530-5 539.
[5]Cha Robert,Rick Steven W,Jungwirth Pavel,et al. The orientation and charge of water at the hydrophobic oil droplet—water interface[J]. Journal of the American Chemical Society,2011,133( 26) : 10 204-10 210.
[6]Li Zhao,Cheng Jinpei,Parker Vernon D. Reactions of the simple nitroalkanes with hydroxide ion in water. Evidence for a complex mechanism[J]. Organic & Biomolecular Chemistry,2011,9( 12) : 4 563-4 569.
[7]冯亚青,王利军,陈立功. 助剂化学及工艺学[M]. 北京: 化学工业出版社, 1997. Feng Yaqing,Wang Lijun,Chen Ligong. Additive Chemistry and Technology[M]. Beijing: Chemistry Industry Press,1997. ( in Chinese)
[8]杜翠红,魏文珑. 磷酸三酯合成工艺的改进[J]. 太原理工大学学报, 1998, 29( 6) : 610-612. Du Cuihong,Wei Wenlong. Improvement of the technology of trialkyl phosphate[J]. Journal of Taiyuan University of Technology, 1998, 29( 6) : 610-612. ( in Chinese)
[9]赵占杰,耿瑞增,顿士勇. 磷酸三苯酯反应机理的研究[J]. 河北冶金, 2003( 3) : 20-21. Zhao Zhanjie,Geng Ruizeng,Dun Shiyong. Research about reaction mechanism of triphenyl-ester phosphate[J]. Hebei Metallurgy, 2003,( 3) : 20-21. ( in Chinese)
[10]郑学明,刘凤林,巫云龙. 关于磷酸三芳基酯收率影响因素的研究[J]. 河北化工, 1992( 4) : 23-25. Zheng Xueming,Liu Fenglin,Wu Yunlong. A study of influential factors on recovery of triarylphosphate[J]. Hebei Chemical Engineering and Industry,1992( 4) : 23-25. ( in Chinese)
[11]Sagar A D,Shinde N A,Bandgar B P. Microwave-assisted synthesis of triaryl phosphates[J]. Org Prep Proced Int,2000, 32( 3) : 269-271.
[12]沈宏一,曹飞,武红丽,等. 相转移催化合成磷酸三苯酯[J]. 塑料助剂, 2007, 63( 3) : 14-16. Shen Hongyi,Cao Fei,Wu Hongli,et al. Synthesis of triphenyl phosphate with phase transfer catalysis[J]. Plastics Additives, 2007, 63( 3) : 14-16. ( in Chinese)
[13]靳通收,刘利宾,姚剑申,等. 常温下合成磷酸三苯酯的研究[J]. 有机化学, 2005, 25( 5) : 595-597. Jin Tongshou,Liu Libin,Yao Jianshen,et al. Study on the synthesis of triphenyl phosphate at room temperature[J]. Chinese Journal of Organic Chemistry,2005, 25( 5) : 595-597. ( in Chinese)

备注/Memo

备注/Memo:
基金项目: 江苏省科技厅产学研前瞻性联合研究资助项目( BY2010105) .通讯联系人: 职慧珍,讲师,研究方向: 绿色有机合成、阻燃剂. E-mail: zhihuizhen@163. com
更新日期/Last Update: 2013-03-11