[1]张叶,于春红,杨锦飞,等.低聚有机膦酸酯阻燃剂的合成[J].南京师范大学学报(工程技术版),2008,08(02):056-58.
　Zhang Ye,Yu Chunhong,Yang Jinfei.Synthesis of Low-polymeric Organic Phosphonate Flame Retardant[J].Journal of Nanjing Normal University(Engineering and Technology),2008,08(02):056-58.
点击复制

低聚有机膦酸酯阻燃剂的合成
分享到：

南京师范大学学报（工程技术版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
08卷
期数:
2008年02期
页码:
056-58
栏目:
出版日期:
2008-06-30

文章信息/Info

Title:
Synthesis of Low-polymeric Organic Phosphonate Flame Retardant
作者:
张叶;于春红;杨锦飞;
南京师范大学化学与环境科学学院, 江苏南京210097
Author(s):
Zhang Ye; Yu Chunhong; Yang Jinfei
School of Chemistry and Environmental Science,Nanjing Normal University,Nanjing 210097,China
关键词:
低聚有机膦酸酯;  阻燃剂;  合成
Keywords:
low-po lym er ic organ ic phosphonate;  flam e retardant;  synthesis
分类号:
TQ314.248;TQ265.11
摘要:
以五氧化二磷、甲基膦酸二甲酯(DMMP)、乙二醇为原料,乙醇为调节剂,辛酸亚锡为催化剂,制备了一种低聚有机膦酸酯阻燃剂.讨论了影响反应的主要因素,用红外光谱分析了该阻燃剂的结构.确定优化的反应条件为:n(DMMP)∶n(P2O5)为1.5∶1,反应温度80~90℃,反应时间2~4 h,产率达到93.8%.反应过程中加入无水乙醇,能使产品的颜色及黏度得到很好的控制.
Abstract:
A k ind of low-po lym er ic org an ic phosphate flam e retardantw as synthesized by a mod ified preparation using P2O5, dim e thy lm ethy l phosphonate ( DMM P) and ethy lene g lyco l as precursors, and stannous o ctoate as cata lyst. IR technique w as used to characterize its chem ical structu re. Exam ining the reaction cond itions showed that when n( DMMP) Bn( P2O5 ) = 1:5:1, reaction tem pe ra ture keeping at 80~ 90℃, reaction tim e keep ing at 2~ 4 h. Unde r the abov e cond itions, synthetic productiv ity can reach 93.8%. The co lor and v isco sity of the product can be w ell contro lled by adding e thano l to the rehospha te, flam action.

参考文献/References:

[ 1] 王良恩, 吴燕翔, 朱跃姿. 缩聚磷酸苯酯的研制[ J]. 福州大学学报: 自然科学版, 1995, 23( 1): 89-91.
W ang Liangen, Wu Yanx iang, Zhu Yuez.i Synthesis of the po lypheny l phospha te[ J] . Journal of Fuzhou Un iversity: Natural Sc ience Edition, 1995, 23( 1): 89-91. ( in Chinese)
[ 2] 汪朝阳, 赵耀明. 聚磷酸酯阻燃剂研究进展[ J]. 塑料, 2003, 3( 32) : 1-5.
W ang Zhaoyang, Zhao Yaom ing. Recent progresses in po lyphosphate esters flam e re tardan ts[ J]. Plastic, 2003, 3( 32) : 1-5.( in Chinese)
[ 3] 王新龙, 韩平. 有机磷阻燃剂研究进展[ J]. 精细石油化工进展, 2002, 3( 6): 33-39.
W ang Xinlong, H an Ping. Prog ress on study o f o rganophosphorous fire retardant[ J]. Advances in F ine Pe tro chem ica ls, 2002,3( 6): 33-39. ( in Chinese)
[ 4] 贺峥杰, 陈文彬, 唐除痴. 有机磷阻燃剂研究进展[ J]. 化学工业与工程, 1997, 14: 43-49.
H e Zheng jie, ChenW enb in, Tang Chuch .i Progress in o rganophosphorous flam e re tardants[ J]. Chem ica l Industry and Engineering, 1997, 14: 43-49. ( in Ch inese)
[ 5] Br ight D A, Dashevsky S, Moy P Y, e t a.l Reso rcino l B is( dipheny l phosphate), a non-ha logen flame- re tardan t additive[ J].Jou rnal of V iny l and Add itive Techno logy, 1997( 3): 170-174.
[ 6] 王新龙, 朱绪光, 宋晔, 等. 双酚A磷酸酯三甲苯酯的合成研究[ J] . 精细石油化工进展, 2001, 2( 5): 11-13.
W ang X inlong, Zhu Xuguang, Song Ye, et a.l Study on synthesis o f b isphenol A phospha te o ligom ers as flam e re tardant [ J]. Advances in F ine Petrochem icals, 2001, 2( 5): 11-13. ( in Ch inese)
[ 7] 朱平, 王炳, 王仑, 等. 无甲醛耐久阻燃剂的制备及应用[ J]. 纺织学报, 2005, 26( 6): 112-114.
Zhu Ping,W ang B ing,W ang Lun, et a.l Preparation and app lica tion of form a ldehyde free durab le flam e retardant[ J]. Journal o f Tex tile Research, 2005, 26( 6): 112-114. ( in Ch inese)
[ 8] Ra lph B Fear ing, Ba rdon ia N Y. Po ly ( oxyorg anophaspha te /phosphona te) and process for preparing: USA, 898241 [ P].1980-04-22.

相似文献/References:

[1]周浩,王丹,张士磊,等.双季戊四醇二亚磷酸酯阻燃剂的合成[J].南京师范大学学报(工程技术版),2010,10(02):048.
　Zhou Hao,Wang Dan,Zhang Shilei,et al.Synthesis of Fire Retardants of Dipentaerythritol Diphosphonate Ester[J].Journal of Nanjing Normal University(Engineering and Technology),2010,10(02):048.
[2]严慧,杨智中,杨锦飞,等.环状磷酸酯阻燃剂Antiblaze的合成[J].南京师范大学学报(工程技术版),2009,09(01):053.
　Yan Hui,Yang Zhizhong,Yang Jinfei.Synthesis of Fire Retardant Cyclic Phosphonate Ester[J].Journal of Nanjing Normal University(Engineering and Technology),2009,09(02):053.
[3]黄东平,顾慧丹,张叶,等.双酚A双(二苯基磷酸酯)阻燃剂的合成[J].南京师范大学学报(工程技术版),2006,06(04):030.
　HUANG Dongping,GU Huidan,ZHANG Ye,et al.Synthesis of Bisphenol-A Bis(Diphenyl Phosphate) Flame Retardant[J].Journal of Nanjing Normal University(Engineering and Technology),2006,06(02):030.
[4]袁相爱,杨锦飞,李丽.间苯二酚磷酸酯阻燃剂的合成研究[J].南京师范大学学报(工程技术版),2005,05(01):080.
　YUAN Xianga,i YANG Jinfe,i LI Li.Study on Synthesis of Resorcin Phosphate as F lame Retardant[J].Journal of Nanjing Normal University(Engineering and Technology),2005,05(02):080.
[5]杨建伟,李丽,杨锦飞.焦磷酸蜜胺的合成与分析[J].南京师范大学学报(工程技术版),2004,04(02):014.
　YANG Jianwei,LI Li,YANG Jinfei.Synthesis and Analysis of Melamine Pyrophosphate[J].Journal of Nanjing Normal University(Engineering and Technology),2004,04(02):014.
[6]郑丽卿,杨锦飞.阻燃剂得克隆(DCRP)的合成[J].南京师范大学学报(工程技术版),2003,03(04):015.
　Zheng Liqing,Yang Jinfei.Study on the Synthesis of Flame Retardant DCRP[J].Journal of Nanjing Normal University(Engineering and Technology),2003,03(02):015.

备注/Memo

备注/Memo:
基金项目: 江苏省科技攻关基金( 2006103S90083 )资助项目.
通讯联系人: 杨锦飞, 教授, 研究方向: 有机合成与阻燃剂. E-m ail:yang jinfei@n jnu. edu. cn
更新日期/Last Update: 2013-04-24