[1]李 丽,杨锦飞,朱 媛.阻燃剂全氯五环癸烷的合成及应用研究[J].南京师范大学学报(工程技术版),2008,08(01):055-58.
　Li Li,Yang Jinfei,Zhu Yuan.Study on the Synthesis and Application of Flame Retardant Perchloropentacyclodecan[J].Journal of Nanjing Normal University(Engineering and Technology),2008,08(01):055-58.
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阻燃剂全氯五环癸烷的合成及应用研究
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南京师范大学学报（工程技术版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
08卷
期数:
2008年01期
页码:
055-58
栏目:
出版日期:
2008-03-30

文章信息/Info

Title:
Study on the Synthesis and Application of Flame Retardant Perchloropentacyclodecan
作者:
李  丽1;  杨锦飞2;  朱 媛1
1. 南京晓庄学院化学系, 江苏南京210041; 2. 南京师范大学化学与环境科学学院, 江苏南京210097
Author(s):
Li Li1; Yang Jinfei2; Zhu Yuan1
1.Department of Chemistry,Nanjing Xiaozhuang College,Nanjing 210041,China;2.School of Chemistry and Environmental Science,Nanjing Normal University,Nanjing 210097,China
关键词:
阻燃剂;  全氯五环癸烷;  合成
Keywords:
flam e re tardant;  Perch lo ropentacyclodecan;  synthes is
分类号:
TQ314.248
摘要:
以六氯环戊二烯为原料,无水三氯化铝为催化剂,通过聚合反应合成了阻燃剂全氯五环癸烷.通过正交实验研究了影响反应的因素,得出最佳工艺条件为:催化剂用量1.5%,反应温度90℃,反应时间2h.并对其在不同材料中的阻燃性能进行了测试,结果表明全氯五环癸烷对聚合物材料的阻燃效果好.
Abstract:
In th is paper, flam e re tardant Perch lo ropentacyclodecan is syn thesized by reaction o f hex ach lorocyclopentad iene through A lC l3 as the cata lyzer. In the course of synthes is, through the orthogonal design the var ious reaction cond-i tions are discussed. So the optim al reac tion cond itions a re confirm ed: the am ount of cata ly st is 1. 5 percent, reaction tim e is 2 hours, and the reaction tem pe rature is 90℃ . A t last, the perform ances in d ifferentm ater ia ls are tested. The resu lts show that Perch lo ropentacyclodecan is an effective flame re tardant for the po lym er ic ma teria ls.

参考文献/References:

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[ 7] 黄青松, 张军, 王立春, 等. 不同卤素阻燃剂协同阻燃LDPE的研究[ J] . 现代塑料加工应用, 2006, 18( 2): 39- 39.
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备注/Memo

备注/Memo:
基金项目: 江苏省科技攻关基金( 2006203SB 90083)资助项目.
作者简介: 李丽( 1979-) , 女, 助教, 研究方向: 有机化学及精细化学品. E-ma il: baby lili2003@ 126. com
通讯联系人: 杨锦飞( 1956-) , 教授, 研究方向: 有机化学和阻燃剂及药物中间体合成. E-m ail:yangjinfei@ n jnu. edu. cn
更新日期/Last Update: 2013-04-24